Humidity Adaptive Antifreeze Hydrogel Sensor for Intelligent Control and Human‐Computer Interaction

Abstract Conductive hydrogels have emerged as ideal candidate materials for strain sensors due to their signal transduction capability and tissue‐like flexibility, resembling human tissues. However, due to the presence of water molecules, hydrogels can experience dehydration and low‐temperature freezing, which greatly limits the application scope as sensors. In this study, an ionic co‐hybrid hydrogel called PBLL is proposed, which utilizes the amphoteric ion betaine hydrochloride (BH) in conjunction with hydrated lithium chloride (LiCl) thereby achieving the function of humidity adaptive. PBLL hydrogel retains water at low humidity (<50%) and absorbs water from air at high humidity (>50%) over the 17 days of testing. Remarkably, the PBLL hydrogel also exhibits strong anti‐freezing properties (−80 °C), high conductivity (8.18 S m −1 at room temperature, 1.9 S m −1 at −80 °C), high gauge factor (GF approaching 5.1). Additionally, PBLL hydrogels exhibit strong inhibitory effects against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus), as well as biocompatibility. By synergistically integrating PBLL hydrogel with wireless transmission and Internet of Things (IoT) technologies, this study has accomplished real‐time human‐computer interaction systems for sports training and rehabilitation evaluation. PBLL hydrogel exhibits significant potential in the fields of medical rehabilitation, artificial intelligence (AI), and the Internet of Things (IoT).