材料科学
半导体
热电效应
热电材料
凝聚态物理
高熵合金
热力学
工程物理
纳米技术
复合材料
光电子学
热导率
微观结构
物理
工程类
作者
Yingchao Wei,Zheng Ma,Wang Li,Chengjun Li,Boyu Yang,Chengwei Sun,Shuangfu Gang,Wenguang Zhang,Hui Long,Xin Li,Qinghui Jiang,Dan Zhang,Yubo Luo,Junyou Yang
标识
DOI:10.1002/adfm.202313719
摘要
Abstract Exploring N‐type High‐entropy materials with both high thermoelectric and mechanical properties is highly desirable for all‐high‐entropy thermoelectric generators (TEGs) since the thermoelectric and mechanical properties of N‐type one are largely behind its P‐type counterparts. Herein, a new rock‐salt structure N‐type high entropy thermoelectric AgBiPbSe 2 S is introduced with a bandgap of ≈0.43 eV. The atomic radii difference of each component results in a large lattice distortion of 0.246, leading to a low thermal conductivity of 0.36 W m −1 K −1 at 823 K. The figure of merit ( ZT ) reaches 0.6 for AgBiPbSe 2 S at 823 K. Moreover, Ag 2 Se precipitates are included in AgBiPbSe 2 S to filter low energy carriers for high Seebeck coefficients and to scatter phonons with nanoscale wavelength for ultralow lattice thermal conductivities. Consequently, a peak ZT of ≈1.18 at 823 K and an average ZT of 0.60 at 400–823 K are obtained for Ag 1.02 BiPbSe 2 S. More importantly, high mechanical properties are also obtained in Ag 1.02 BiPbSe 2 S, of which the Vickers hardness and flexural strength are ≈209 Hv and 32 MPa, respectively, originating from the enhanced lattice friction by chemical short‐range disorder (i.e., high entropy effect) and dispersion strengthening caused by Ag 2 Se nanoprecipitates.
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