Dissolution behavior of ionic liquids for different ratios of lignin and cellulose in the preparation of nanocellulose/lignin blends

Lignin is regarded as a potential solution for boosting the strength of cellulose-based products. However, the mechanism of co-solubilization for lignin and cellulose has not been investigated. In this study, the effect of lignin content on the interaction between lignin and nanocellulose during lignin/cellulose co-dissolution was examined. The results revealed that lignin binds to nanocellulose throughout the dissolution process to limit the degradation of cellulose and to prepare nanocellulose/lignin composites. Moreover, the S units in lignin were more likely to interact with cellulose during the dissolution process, whereas the G units were more likely to condense. However, when the lignin content exceeded 30 wt%, the excess lignin created a severe condensation reaction, which led to a decrease in the lignin content bound to cellulose, resulting in an unequal dissolution of cellulose. Thus, a small amount of lignin attached to cellulose during the co-dissolution of lignin and cellulose inhibits cellulose degradation and can be utilized to create nanocellulose/lignin to extend the potential applications of nanocellulosic materials.