Insight into the Superior Lithium Storage Properties of Ultrafine CoO Nanoparticles Confined in a 3 D Bimodal Ordered Mesoporous Carbon CMK‐9 Anode

Abstract Ultrafine CoO particles immobilized into the mesopores of three‐dimensional cubic bimodal ordered mesoporous carbon CMK‐9 is successfully prepared by using a combination of nanocasting and wet‐impregnation methods. It is found that the cubic bimodal interconnected mesoporous framework of CMK‐9 plays a crucial role in achieving the excellent electrochemical performances by assisting the rapid mass and charge transfer. Among the prepared nanocomposites, CoO(10)@CMK‐9 delivers a discharge capacity of 830 mAh g −1 after 200 cycles at a current density of 100 mA g −1 in lithium‐ion batteries. At a higher current density of 1000 mA g −1 , the anode presents an outstanding discharge capacity of 636 mAh g −1 after 200 cycles. In sodium‐ion batteries, the anode provides a discharge capacity of 296 mAh g −1 after 250 cycles at a current density of 100 mA g −1 . The remarkable performances of CoO(10)@CMK‐9 demonstrate the promising potentials of the nanocomposite as the anode for rechargeable batteries.