分散性
稀土
材料科学
纳米晶
纳米材料
纳米技术
配体(生物化学)
产量(工程)
微型反应器
氟化物
组合化学
化学
催化作用
无机化学
有机化学
高分子化学
受体
冶金
生物化学
作者
Stan Najmr,Davit Jishkariani,Katherine C. Elbert,Bertrand Donnio,Christopher B. Murray
出处
期刊:Nanoscale
[The Royal Society of Chemistry]
日期:2017-01-01
卷期号:9 (24): 8107-8112
被引量:5
摘要
Rare-earth nanocrystals (RE NCs) are a valuable class of nanomaterials due to their ability to bring the attractive properties of rare earth bulk crystals to biomedical applications and solution-processable engineering. Of the bottom-up synthesis approaches, solvothermal methods yield highly crystalline and monodisperse RE NCs. Herein, we report a polycatenar ligand controlled synthesis of RE NCs using a semi-combinatorial approach with a microreactor setup that enables the investigation of the influences of several reaction parameters on the growth of the RE NCs. This approach enabled the discovery of conditions that yield highly monodisperse elongated plates with neutral, positive, and negative curvatures, as well as provide evidence of the formation of chiral morphologies.
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