化学
催化作用
芳基
镍
联轴节(管道)
组合化学
有机化学
高分子化学
冶金
材料科学
烷基
作者
Mark Stradiotto,Ryan S. Sawatzky,M.J. Ferguson
出处
期刊:Synlett
[Georg Thieme Verlag KG]
日期:2017-05-02
卷期号:28 (13): 1586-1591
被引量:15
标识
DOI:10.1055/s-0036-1588806
摘要
Synthesis and characterization of the new air-stable pre-catalyst (DPEPhos)Ni(2-mesityl)Br (C1) is reported, along with the application of this pre-catalyst in the cross-coupling of secondary amines/azoles with activated (hetero)aryl chlorides to afford tertiary (hetero)anilines. The performance of C1 in these cross-couplings is competitive with some of the best and/or most widely employed nickel catalysts for such transformations.
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