Solvent-mediated switching between oxidative addition and addition–oxidation: access to β-hydroxysulfides and β-arylsulfones by the addition of thiols to olefins in the presence of Oxone

Solvent-switching allows formation of either β-hydroxy-2-arylethyl aryl sulfides or 2-arylethyl aryl sulfones exclusively in thiol–ene ‘click’ reactions conducted with Oxone.