Flexible and Robust Piezoelectric Polymer Nanocomposites Based Energy Harvesters.

Environment friendly, flexible, and robust sensors have attracted considerable research attention due to their potential for a wide range of devices in energy generation and harvesting, sensing, and biomedical applications. In this manuscript, we demonstrate a lead-free, solution processed flexible piezoelectric energy generator based on a nanocomposite film, consisting of MgO nanoparticles of sizes around <50 nm, embedded in poly(vinylidene difluoride) [PVDF] and its copolymer with trifluoroethylene, that is, P(VDF-TrFE) matrix. Piezoelectric, ferroelectric, and leakage current measurements made on samples with various concentrations of MgO nanoparticles revealed a dramatic improvement in these characteristics at 2 wt % MgO with nearly 50% increase in the piezoelectric coefficient as compared to pure P(VDF-TrFE), attributed to the preferred conformation of P(VDF-TrFE) chain, improved crystallinity of the P(VDF-TrFE) matrix, and uniform distribution of nanoparticles. Assessment of the interactions between...