纳米复合材料
石墨烯
锡
材料科学
硫化物
化学工程
碳纤维
硫化铁
锂(药物)
电化学
循环伏安法
碳纳米管
氧化锡
复合数
纳米颗粒
无机化学
电极
石墨氮化碳
兴奋剂
纳米技术
法拉第效率
拉曼光谱
作者
Tiantian Ma,Li Sun,Qun Niu,Yinghao Xu,Kangle Zhu,Xianghong Liu,Xin Guo,Jun Zhang
标识
DOI:10.1016/j.electacta.2019.01.104
摘要
Abstract Tin sulfides have attracted significant interests as the anode materials of lithium-ion batteries (LIBs) due to their high capacity and layered structure. However, metal sulfides suffer from a fast capacity decay caused by the large volume change during cycling, and poor conductivity. In this work, we report on a rational design of lamellar nanostructure consisting of N-doped carbon layers, graphene nanosheets, and SnS nanoparticles. The SnS/graphene nanosheets with and without N-carbon coating have been investigated as the anode for LIBs to study the structure effect. It is found that N-carbon/SnS/graphene nanosheets deliver a high reversible capacity of 840 mA h g−1 after 150 cycles at a current density of 100 mA g−1 and higher rate properties in comparison to SnS/graphene. The improved electrochemical performances are attributed to the special lamellar structure with a combined synergic effect derived from the N-carbon coating layers and graphene nanosheets, which conduce to a faster lithium diffusion dynamics in the composite nanosheets, which has been analyzed by electrochemical impedance spectroscopy. This work propose an efficient pathway to manipulate metal sulfides based nanomaterials for use as anodes in LIBs with enhanced lithium storage performances.
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