直接的
镁
化学
反应性(心理学)
杂蒽
酰胺
光化学
催化作用
计算化学
药物化学
有机化学
医学
物理
替代医学
病理
核物理学
单重态
激发态
作者
Rahul Mondal,Matthew J. Evans,Thayalan Rajeshkumar,Laurent Maron,Cameron Jones
标识
DOI:10.1002/anie.202308347
摘要
Abstract The activation of dinitrogen (N 2 ) by transition metals is central to the highly energy intensive, heterogeneous Haber–Bosch process. Considerable progress has been made towards more sustainable homogeneous activations of N 2 with d‐ and f‐block metals, though little success has been had with main group metals. Here we report that the reduction of a bulky magnesium(II) amide [( TCHP NON)Mg] ( TCHP NON=4,5‐bis(2,4,6‐tricyclohexylanilido)‐2,7‐diethyl‐9,9‐dimethyl‐xanthene) with 5 % w/w K/KI yields the magnesium‐N 2 complex [{K( TCHP NON)Mg} 2 (μ‐N 2 )]. DFT calculations and experimental data show that the dinitrogen unit in the complex has been reduced to the N 2 2− dianion, via a transient anionic magnesium(I) radical. The compound readily reductively activates CO, H 2 and C 2 H 4 , in reactions in which it acts as a masked dimagnesium(I) diradical.
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