Genesis of Danping bauxite (Northern Guizhou, China) and associated lithium: Evidence from LA-ICP-MS analysis of Al-bearing minerals

铝土矿 高岭石 地球化学 伊利石 锂(药物) 地质学 微量元素 矿物 电感耦合等离子体质谱法 矿物学 绿泥石 粘土矿物 蒙脱石 化学 冶金 材料科学 质谱法 石英 古生物学 有机化学 色谱法 医学 内分泌学
作者
Bing Liu,Peiwen Chen,Tianshun Wang,Guotao Sun,Mengyu Duan,Kejun Hou,Qingdong Zeng,Yong Fu
出处
期刊:Journal of Geochemical Exploration [Elsevier BV]
卷期号:262: 107464-107464
标识
DOI:10.1016/j.gexplo.2024.107464
摘要

Lithium (Li), as an essential element of green new energy technology, is a global strategic resource. Sedimentary Li is primarily associated with bauxite, with a local grade of >1000 ppm, and has a huge utilization prospect. However, fine particles limit the study of the occurrence of Li. The Danping bauxite deposit, located in northern Guizhou, China, which accompanying considerable Li resources. In this study, in situ elemental concentration analyses were conducted by laser ablation-inductively coupled plasma-mass spectrometry. The analysis results show that Li is mainly enriched at the bottom and top of the aluminiferous rock series, and the Li content at the top is higher (615.98–3289.98 ppm). Li content is positively correlated with Mg and Fe content, indicating that chlorite is a potential Li-bearing mineral. K content of <10,000 ppm, K content is positively correlated with Li content, indicating that illite may also be a Li-bearing mineral. Kaolinite, transformed from montmorillonite, may also have a high Li content. Ga content is always positively correlated with Al content, indicating that Ga mainly occurs in diaspores. Bauxite has similar Nb/Ta and Zr/Hf ratios to the underlying Hanjiadian Formation shale, as well as the same positive Ce anomalies (negative anomalies in Huanglong Formation), indicating that the ore-forming material of Danping is primarily derived from the underlying Hanjiadian Formation.
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