微尺度化学
材料科学
沉积(地质)
电化学
纳米技术
化学工程
电极
工程类
古生物学
化学
数学教育
数学
物理化学
沉积物
生物
作者
Lei Wang,Xiaobo Liao,Siyu Chen,Wenlin Wu,Tong Li,Jian Zhuang,Yong Q. Cai
标识
DOI:10.1002/adem.202301758
摘要
Micro‐nano scale 3D printing is attracting attention as an alternative manufacturing method for a variety of applications in electronic information, biomedical, and sensing devices. Localized electrochemical deposition (LECD) based on nanopipettes is naturally superior and economical for the manufacturing of high‐freedom, impurity‐free metal conductors. However, flexible printing sacrifices roughness and straightness. Therefore, the present study initially establishes a simulation model for LECD and subsequently analyzes the key factors that influence the quality and stability of the deposited structure. Furthermore, an effective solution is proposed to enhance the surface quality. Second, a constant deposition current control method based on fuzzy proportional–intergral–derivaite (PID) is proposed to effectively suppress the fluctuation and improve the stability and quality of the deposited structure. Finally, compared with the open‐loop control method, the proposed constant current control method can reduce the radial fluctuation of the copper pillar structure by 87%, and effectively improve the surface quality of the structure. The proposed method provides a new idea to carry out LCED‐based 3D printing with high resolution at the micro‐nano scale.
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