Infinite Self‐Propulsion of Circularly On/Discharged Droplets

Abstract Self‐propulsion of droplets in a controlled and long path at a high‐speed is crucial for organic synthesis, pathological diagnosis and programable lab‐on‐a‐chip. To date, extensive efforts have been made to achieve droplet self‐propulsion by asymmetric gradient, yet, existing structural, chemical, or charge density gradients can only last for a while (<50 mm). Here, this work designs a symmetrical waved alternating potential (WAP) on a superhydrophobic surface to charge or discharge the droplets during the transport process. By deeply studying the motion mechanisms for neutral droplets and charged droplets, the circularly on/discharged droplets achieve the infinite self‐propulsion (>1000 mm) with an ultrahigh velocity of meters per second. In addition, after permutation and combination of two motion styles of the droplets, it can be competent for more interesting work, such as liquid diode and liquid logic gate. Being assembled into a microfluidic chip, the strategy would be applied in chemical synthesis, cell culture, and diagnostic kits.