超级电容器
过电位
材料科学
塔菲尔方程
分解水
尖晶石
电化学
电化学能量转换
氧化钴
化学工程
电极
储能
析氧
锰
钴
纳米技术
冶金
化学
催化作用
物理化学
生物化学
功率(物理)
物理
光催化
量子力学
工程类
作者
Muhammad Zahir Iqbal,Misbah Shaheen,Umair Aftab,Zubair Ahmad,Muhammad Yameen Solangi,Muhammad Ishaque Abro,Saikh Mohammad Wabaidur
出处
期刊:Energy & Fuels
[American Chemical Society]
日期:2024-01-19
卷期号:38 (3): 2416-2425
被引量:3
标识
DOI:10.1021/acs.energyfuels.3c03444
摘要
Owing to their potential usage and great electrochemical performance, transition metal oxides (TMOs) are attracting enormous interest to be scrutinized for the energy-storage and conversion domain. Our work describes the electrochemical response of spinel transition metal oxides (Co3O4 and MnCo2O4) for electrochemical water splitting (oxidation evolution reaction (OER)) and hybrid energy-storage devices. After a comprehensive study of the structure and morphology, the synthesized materials were initially evaluated for the OER performance. Mn-doped Co3O4 performed better for OER due to the inclusion of Mn ions in the spinel structure. For the OER activity, the fabricated electrode showed an overpotential of 311 mV and a Tafel slope of 71 mV/dec upon obtaining the good performance of Mn-doped Co3O4 for OER; it was further utilized for energy-storage application by fabricating its hybrid supercapacitor device with activated carbon. The hybrid supercapacitor showed a better energy (36 W h/kg) and power density (4274 W/kg) relatively. Moreover, the semiempirical approach was adapted to further elaborate the experimental results obtained. The significant response of the developed electrodes enhances their potential for future energy-storage and conversion applications.
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