Novel Z-scheme Nb2O5/C3N5 photocatalyst for boosted degradation of tetracycline antibiotics by visible light-assisted activation of persulfate system

过硫酸盐 降级(电信) 光催化 异质结 光致发光 光化学 四环素类抗生素 可见光谱 污染物 电子顺磁共振 材料科学 煅烧 化学工程 化学 四环素 光电子学 催化作用 有机化学 计算机科学 物理 电信 生物化学 抗生素 工程类 核磁共振
作者
Wenning Liao,Zhiquan Yang,Ying Wang,Shuai Li,Caiyun Wang,Zhuolin Zhou
出处
期刊:Chemical Engineering Journal [Elsevier BV]
卷期号:478: 147346-147346 被引量:24
标识
DOI:10.1016/j.cej.2023.147346
摘要

Photocatalytic-assisted activation of persulfate (PDS) is regarded as a promising method for the rapid and efficient degradation of refractory pollutants in the water environment. In this study, a novel Nb2O5/C3N5 (NOCN) p-n heterojunctions composite was created by loading n-type Nb2O5 onto p-type C3N5 via an in-situ facile one-step calcination method. The NOCN/PDS system exhibited excellent performance in degrading tetracycline (TC) antibiotics under visible light and had great cyclic stability. The degradation efficiency of the coupled system reached 95 %, surpassing the pure C3N5 and PDS systems by 3.5 times and 2.4 times, respectively. The degradation rate of target pollutants was improved by the coupled system with the photocatalytic activation of PDS. The photogenerated electrons (e-) in NOCN were able to activate PDS effectively, which facilitated the creation of more reactive species. The Photoluminescence (PL) and other photoelectrochemical data demonstrated that the interfacial charge separation and photoresponsivity were remarkably enhanced in the coupled system. According to Mott-Schooky and electron spin resonance (ESR) characterization, it was confirmed that the reaction mechanism was the Z-scheme charge transfer mechanism based on p-n heterojunctions in the NOCN/PDS system. In addition, LC-MS analyses, TOC monitoring and biotoxicity analyses detected that the target pollutants were degraded to weakly bio-toxic micromolecules. In conclusion, this work provides valuable insights into the application of visible light-activated PDS technology in the degradation of organic pollutants, highlighting its potential for practical implementation.
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