Highly Efficient Low-Valent Tungsten-Catalyzed Deoxygenative Reduction of Tertiary Amides to Amines with Pinacolborane
化学
催化作用
还原（数学）
钨
组合化学
有机化学
几何学
数学
作者
Biao Cheng,Jingchao Xv,Xiang Ren,Yuanyuan Li,Xiaoming Ji,Zhan Lu
出处
期刊：Organic chemistry frontiers [The Royal Society of Chemistry] 日期：2025-01-01
标识
DOI：10.1039/d4qo02340d
摘要
A highly efficient low-valent tungsten-catalyzed deoxygenative reduction of tertiary amides to amines with pinacolborane (HBpin) is developed. This protocol uses commercially available W(CO)6 as catalyst in a solution of hexane...
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