超临界流体
米糠油
异构化
催化作用
共轭亚油酸
化学
双金属片
亚油酸
麸皮
有机化学
脂肪酸
原材料
作者
Fei Wu,Wen Zhong,Yajie Dai,Xiaohuan Hu,Zhe Huang,Shan Gao,Fengying Xie,Dianyu Yu
摘要
Summary In this work, the catalytic efficiency and influencing factors of supported bimetallic catalysts for the synchronised isomerisation of rice bran oil (RBO) to produce conjugated linoleic acid (CLA)‐rich RBO under supercritical conditions were investigated. The morphology and internal composition of the metal catalysts were analysed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM), which revealed that Ru and Pd were successfully supported by ultra‐stable Y(USY). The catalyst and oil were synchronously isomerised in the supercritical CO 2 environment, and the change in the fatty acid composition of the oil was measured by gas chromatography. The results showed that when the CO 2 pressure was 8.0 MPa, the catalyst addition was 5% and the reaction temperature was 160 °C, the conversion of linoleic acid in the RBO catalysed by Ru‐Pd/USY was 68.25 ± 0.08%, and the produced oil met the edible standard.
科研通智能强力驱动
Strongly Powered by AbleSci AI