多孔介质
松弛法
多孔性
纳米孔
化学物理
渗吸
材料科学
放松(心理学)
相(物质)
化学
纳米技术
自旋回波
复合材料
磁共振成像
有机化学
医学
社会心理学
生物
发芽
植物
放射科
心理学
作者
Benjamin Maillet,Rahima Sidi‐Boulenouar,Philippe Coussot
出处
期刊:Langmuir
[American Chemical Society]
日期:2022-12-05
卷期号:38 (49): 15009-15025
被引量:23
标识
DOI:10.1021/acs.langmuir.2c01918
摘要
Porous media containing voids which can be filled with gas and/or liquids are ubiquitous in our everyday life: soils, wood, bricks, concrete, sponges, and textiles. It is of major interest to identify how a liquid, pushing another fluid or transporting particles, ions, or nutriments, can penetrate or be extracted from the porous medium. High-resolution X-ray microtomography, neutron imaging, and magnetic resonance imaging are techniques allowing us to obtain, in a nondestructive way, a view of the internal processes in nontransparent porous media. Here we review the possibilities of a simple though powerful technique which provides various direct quantitative information on the liquid distribution inside the porous structure and its variations over time due to fluid transport and/or phase changes. It relies on the analysis of the details of the NMR (nuclear magnetic resonance) relaxation of the proton spins of the liquid molecules and its evolution during some process such as the imbibition, drying, or phase change of the sample. This rather cheap technique then allows us to distinguish how the liquid is distributed in the different pore sizes or pore types and how this evolves over time; since the NMR relaxation time depends on the fraction of time spent by the molecule along the solid surface, this technique can also be used to determine the specific surface of some pore classes in the material. The principles of the technique and its contribution to the physical understanding of the processes are illustrated through examples: imbibition, drying or fluid transfers in a nanoporous silica glass, large pores dispersed in a fine polymeric porous matrix, a pile of cellulose fibers partially saturated with bound water, a softwood, and a simple porous inclusion in a cement paste. We thus show the efficiency of the technique to quantify the transfers with a good temporal resolution.
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