阳极
分离器(采油)
材料科学
阴极
电化学
电极
硅
电池(电)
化学工程
离子
储能
光电子学
纳米技术
电气工程
化学
物理
工程类
物理化学
功率(物理)
有机化学
热力学
量子力学
作者
Qinghai Meng,Min Fan,Xin Chang,Hongliang Li,Wenpeng Wang,Yuhui Zhu,Jing Wan,Yaoyao Fiona Zhao,Fuyi Wang,Rui Wen,Sen Xin,Yu‐Guo Guo
标识
DOI:10.1002/aenm.202300507
摘要
Abstract High‐energy lithium‐ion batteries built with silicon‐based anode materials are usually associated with short cycle lives due to mechanical failure at an anode level and more importantly, due to electrochemical failure at a cell level as a result of irreversible consumption of cathode Li during initial charge. (Electro)chemical prelithiation has shown promises to compensate initial Li loss and improve cycling performance of the battery. However, previous strategies applied directly at anode or cathode could raise concerns on safety and degraded electrode structure, and are less compatible with industrial manufacture of batteries. Here, a new concept of prelithiation by lithiation agents supported functional separator, which is highly adaptive to electrode preparation, battery manufacture and formation, and is capable of, by simply adjusting cell voltage, not only replenishing cathode Li loss but re‐uptaking anode Li to inhibit local over‐lithiation and dendrite formation, is shown. By employing the functional separator, a 3‐Ah Li‐ion pouch cell that pairs a silicon‐based anode and a high‐nickel layered oxide cathode demonstrates stable energy output of >330 Wh kg −1 and much improved cycling performance.
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