Design Approach of Lifetime Extending Thermally Activated Delayed Fluorescence Sensitizers for Highly Efficient Fluorescence Devices

Abstract In this work, a design approach of three thermally activated delayed fluorescence (TADF) emitters to extend the device lifetime of the TADF sensitized fluorescent devices was studied. Three TADF materials, 5‐{4,6‐bis[4‐( tert ‐butyl)phenyl]‐1,3,5‐triazin‐2‐yl}‐2‐(10,15‐diphenyl‐10,15‐dihydro‐5 H ‐diindolo[3,2‐ a :3′,2′‐ c ]carbazol‐5‐yl)benzonitrile (tTCNTruX), 4‐[3‐cyano‐4‐(10,15‐diphenyl‐10,15‐dihydro‐5 H ‐diindolo[3,2‐ a :3′,2′‐ c ]carbazol‐5‐yl)phenyl]‐2,6‐diphenylpyrimidine‐5‐carbonitrile (PCNTruX) and 4‐(4‐{10,15‐bis[4‐( tert ‐butyl)phenyl]‐10,15‐dihydro‐5 H ‐diindolo[3,2‐ a :3′,2′‐ c ]carbazol‐5‐yl}‐3‐cyanophenyl)‐2,6‐diphenylpyrimidine‐5‐carbonitrile (PCNtTruX), were synthesized as sensitizers for TADF‐sensitized fluorescent organic light‐emitting diodes. The two tTCNTruX and PCNtTruX TADF emitters were designed to have Dexter energy transfer with blocking groups either in the donor or acceptor unit of the donor–acceptor‐type TADF sensitizer. The TADF materials showed small singlet–triplet energy splitting and a high reverse intersystem crossing (RISC) rate for effective sensitization of the fluorescent emission of the fluorescent emitter. tTCNTruX‐ and PCNtTruX‐sensitized fluorescent devices showed maximum external quantum efficiencies (EQEs) of 17.7 % and 11.5 % in the yellow and red devices, respectively, which were higher than those of TADF‐sensitized devices with the corresponding TADF sensitizer without a blocking group. Moreover, the device lifetime was also extended by employing the tTCNTruX and PCNtTruX sensitizers. This work demonstrated that the tTCNTruX and PCNtTruX sensitizers are effective to improve the maximum EQE and device lifetime of TADF‐sensitized fluorescent devices.