异质结
材料科学
光催化
X射线光电子能谱
量子点
范德瓦尔斯力
纳米技术
复合数
介孔材料
化学工程
光电子学
化学
复合材料
分子
催化作用
生物化学
工程类
有机化学
作者
Fei He,Bicheng Zhu,Bei Cheng,Jiaguo Yu,Wingkei Ho,Wojciech Macyk
标识
DOI:10.1016/j.apcatb.2020.119006
摘要
Herein, two-dimensional (2D) TiO2 mesoporous nanosheets with three to four C3N4 layers grown in situ are employed to design a core–shell 2D/2D van der Waals heterojunction (TiO2/C3N4). Edge-terminated zero-dimensional (0D) Ti3C2 MXene quantum dots (TCQD) are subsequently integrated in the C3N4 surface via electrostatic interactions. The constructed 2D/2D/0D TiO2/C3N4/Ti3C2 composite heterojunction photocatalyst exhibits enhanced CO2 reduction activity compared to TiO2, C3N4, TiO2/C3N4, C3N4/Ti3C2 for CO and CH4 production. A step-scheme (S-scheme) charge transfer mechanism operates for the prepared samples during CO2 reduction, as authenticated by in situ X-ray photoelectron spectroscopy and electron paramagnetic resonance analysis. This study provides a paradigm of a rational structural design for regulating the number and type of heterointerfaces and further insights into the mechanism of multijunction photocatalysts.
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