Spray‐Coating of Catalytically Active MOF–Polythiourea through Postsynthetic Polymerization

A UiO-66-NCS MOF was formed by postsynthetic modification of UiO-66-NH2 . The UiO-66-NCS MOFs displays a circa 20-fold increase in activity against the chemical warfare agent simulant dimethyl-4-nitrophenyl phosphate (DMNP) compared to UiO-66-NH2 , making it the most active MOF materials using a validated high-throughput screening. The -NCS functional groups provide reactive handles for postsynthetic polymerization of the MOFs into functional materials. These MOFs can be tethered to amine-terminated polypropylene polymers (Jeffamines) through a facile room-temperature synthesis with no byproducts. The MOFs are then crosslinked into a MOF-polythiourea (MOF-PTU) composite material, maintaining the catalytic properties of the MOF and the flexibility of the polymer. This MOF-PTU hybrid material was spray-coated onto Nyco textile fibers, displaying excellent adhesion to the fiber surface. The spray-coated fibers were screened for the degradation of DMNP and showed durable catalytic reactivity.