Bimetal-Organic-Framework Derivation of Ball-Cactus-Like Ni-Sn-P@C-CNT as Long-Cycle Anode for Lithium Ion Battery

SmallVolume 13, Issue 27 1700521 Full Paper Bimetal-Organic-Framework Derivation of Ball-Cactus-Like Ni-Sn-P@C-CNT as Long-Cycle Anode for Lithium Ion Battery Correction(s) for this article Bimetal-Organic-Framework Derivation of Ball-Cactus-Like Ni-Sn-P@C-CNT as Long-Cycle Anode for Lithium Ion Battery Ruoling Dai, Weiwei Sun, Li-Ping Lv, Minghong Wu, Hao Liu, Guoxiu Wang, Yong Wang, Volume 17Issue 49Small First Published online: December 9, 2021 Ruoling Dai, Ruoling Dai Department of Chemical Engineering, School of Environmental and Chemical Engineering, Shanghai University, 99 Shangda Road, Shanghai, 200444 P. R. ChinaSearch for more papers by this authorWeiwei Sun, Weiwei Sun Department of Chemical Engineering, School of Environmental and Chemical Engineering, Shanghai University, 99 Shangda Road, Shanghai, 200444 P. R. ChinaSearch for more papers by this authorLi-Ping Lv, Li-Ping Lv Department of Chemical Engineering, School of Environmental and Chemical Engineering, Shanghai University, 99 Shangda Road, Shanghai, 200444 P. R. ChinaSearch for more papers by this authorMinghong Wu, Corresponding Author Minghong Wu mhwu@shu.edu.cn Department of Chemical Engineering, School of Environmental and Chemical Engineering, Shanghai University, 99 Shangda Road, Shanghai, 200444 P. R. ChinaE-mail: mhwu@shu.edu.cn, yongwang@shu.edu.cnSearch for more papers by this authorHao Liu, Hao Liu Department of Chemical Engineering, School of Environmental and Chemical Engineering, Shanghai University, 99 Shangda Road, Shanghai, 200444 P. R. ChinaSearch for more papers by this authorGuoxiu Wang, Guoxiu Wang Centre for Clean Energy Technology, School of Mathematical and Physical Sciences, University of Technology Sydney, Broadway, Sydney, NSW, 2007 AustraliaSearch for more papers by this authorYong Wang, Corresponding Author Yong Wang yongwang@shu.edu.cn Department of Chemical Engineering, School of Environmental and Chemical Engineering, Shanghai University, 99 Shangda Road, Shanghai, 200444 P. R. ChinaE-mail: mhwu@shu.edu.cn, yongwang@shu.edu.cnSearch for more papers by this author Ruoling Dai, Ruoling Dai Department of Chemical Engineering, School of Environmental and Chemical Engineering, Shanghai University, 99 Shangda Road, Shanghai, 200444 P. R. ChinaSearch for more papers by this authorWeiwei Sun, Weiwei Sun Department of Chemical Engineering, School of Environmental and Chemical Engineering, Shanghai University, 99 Shangda Road, Shanghai, 200444 P. R. ChinaSearch for more papers by this authorLi-Ping Lv, Li-Ping Lv Department of Chemical Engineering, School of Environmental and Chemical Engineering, Shanghai University, 99 Shangda Road, Shanghai, 200444 P. R. ChinaSearch for more papers by this authorMinghong Wu, Corresponding Author Minghong Wu mhwu@shu.edu.cn Department of Chemical Engineering, School of Environmental and Chemical Engineering, Shanghai University, 99 Shangda Road, Shanghai, 200444 P. R. ChinaE-mail: mhwu@shu.edu.cn, yongwang@shu.edu.cnSearch for more papers by this authorHao Liu, Hao Liu Department of Chemical Engineering, School of Environmental and Chemical Engineering, Shanghai University, 99 Shangda Road, Shanghai, 200444 P. R. ChinaSearch for more papers by this authorGuoxiu Wang, Guoxiu Wang Centre for Clean Energy Technology, School of Mathematical and Physical Sciences, University of Technology Sydney, Broadway, Sydney, NSW, 2007 AustraliaSearch for more papers by this authorYong Wang, Corresponding Author Yong Wang yongwang@shu.edu.cn Department of Chemical Engineering, School of Environmental and Chemical Engineering, Shanghai University, 99 Shangda Road, Shanghai, 200444 P. R. ChinaE-mail: mhwu@shu.edu.cn, yongwang@shu.edu.cnSearch for more papers by this author First published: 22 May 2017 https://doi.org/10.1002/smll.201700521Citations: 64Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Abstract Metal phosphides are a new class of potential high-capacity anodes for lithium ion batteries, but their short cycle life is the critical problem to hinder its practical application. A unique ball-cactus-like microsphere of carbon coated NiP2/Ni3Sn4 with deep-rooted carbon nanotubes (Ni-Sn-P@C-CNT) is demonstrated in this work to solve this problem. Bimetal-organic-frameworks (BMOFs, Ni-Sn-BTC, BTC refers to 1,3,5-benzenetricarboxylic acid) are formed by a two-step uniform microwave-assisted irradiation approach and used as the precursor to grow Ni-Sn@C-CNT, Ni-Sn-P@C-CNT, yolk–shell Ni-Sn@C, and Ni-Sn-P@C. The uniform carbon overlayer is formed by the decomposition of organic ligands from MOFs and small CNTs are deeply rooted in Ni-Sn-P@C microsphere due to the in situ catalysis effect of Ni-Sn. Among these potential anode materials, the Ni-Sn-P@C-CNT is found to be a promising anode with best electrochemical properties. It exhibits a large reversible capacity of 704 mA h g−1 after 200 cycles at 100 mA g−1 and excellent high-rate cycling performance (a stable capacity of 504 mA h g−1 retained after 800 cycles at 1 A g−1). These good electrochemical properties are mainly ascribed to the unique 3D mesoporous structure design along with dual active components showing synergistic electrochemical activity within different voltage windows. Citing Literature Supporting Information Filename Description smll201700521-sup-0001-S1.pdf257.9 KB Supplementary Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume13, Issue27July 19, 20171700521 RelatedInformation