二苯并噻吩
烟气脱硫
苯并噻吩
多金属氧酸盐
催化作用
加氢脱硫
硫黄
化学
氧化还原
燃料油
化学工程
有机化学
废物管理
噻吩
工程类
作者
Moslem Ahmadian,Mansoor Anbia
出处
期刊:Energy & Fuels
[American Chemical Society]
日期:2021-06-22
卷期号:35 (13): 10347-10373
被引量:63
标识
DOI:10.1021/acs.energyfuels.1c00862
摘要
Nowadays, desulfurization of liquid fuels is inevitable because of strict environmental and industrial regulations on liquid fuels specifications. Hydrodesulfurization (HDS) technology has been used widely to produce fuels with ultralow sulfur content (S ≤ 10 ppm). However, this method is not effective enough for removing refractory sulfur compounds (e.g., benzothiophene, dibenzothiophene, and their derivatives). Consequently, alternative or supplementary desulfurization methods have been rapidly developed in recent years. The oxidative desulfurization (ODS) process is a promising method with high selectivity, low cost, mild reaction conditions, and high efficiency. In the past few decades, the ODS process of fuels by polyoxometalates (POMs) as catalysts have attracted considerable attention, resulting in different works have been published due to their strong acidity, fast and reversible multielectron redox properties, tunable redox properties, as well as thermal, hydrolytic, and oxidative stability. In this review, the removal of S-compounds from fuel oils is investigated via the ODS process using homogeneous and heterogeneous polyoxometalate catalysts. Moreover, the advantages and problems of each system are discussed. Various techniques for reducing their noticeable drawbacks are also presented. Finally, the regeneration of POM catalysts, as an important step in industrial applications, is examined.
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