非随机双液模型
三元运算
热力学
三元数制
化学
液态液体
乙醇
二进制数
可靠性(半导体)
色谱法
活度系数
物理化学
数学
有机化学
物理
算术
计算机科学
功率(物理)
水溶液
程序设计语言
作者
Jun Gao,Lianzheng Zhang,Dongmei Xu,Ying Wei,Zhishan Zhang,Zhifang Cui
标识
DOI:10.1021/acs.jced.5b00436
摘要
Liquid–liquid equilibrium (LLE) data for the ternary system 2,2,3,3,4,4,5,5-octafluoro-1-pentanol + ethanol + water have been reported at (298.15, 308.15, and 318.15) K and 0.1 MPa. The Bachman equation and the Hand equation were used to confirm the reliability of the experimental tie-line data. The experimental data were correlated by the nonrandom two-liquid (NRTL) model, for which the calculated results show good agreement with the ternary LLE data, and the binary interaction parameters of NRTL model were also regressed. Moreover, the distribution coefficients and separation factors in the ternary system were determined by the experimental data.
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