光热治疗
化学
纳米技术
光热效应
吸收(声学)
催化作用
复合材料
有机化学
材料科学
作者
Ziqi Wang,Zhongqing Yang,Zukhra C. Kadirova,Mingnv Guo,Ruiming Fang,Jiang He,Yunfei Yan,Jingyu Ran
标识
DOI:10.1016/j.ccr.2022.214794
摘要
Photothermal catalytic CO2 reduction to solar fuels is one of the most promising technologies for industrial development. Photothermal catalytic CO2 reduction by H2 and CH4 have high fuel production rate and light-to-fuel efficiency, which become pioneer in the industrialization of solar fuels, while the yield of artificial photosynthesis still has a gap with industrialization, the low solar light absorption, photothermal conversion, active site exposure and carrier mobility severely restrict the development from laboratory to industrialization. Photothermal functional structures and materials have become a breakthrough due to excellent full solar spectrum absorption capacity, photothermal conversion properties, and excellent electrical conductivity. In order to bring inspiration to the breakthrough of the bottleneck, this paper reviewed the latest research progress of emerging photothermal functional materials (GDY, MXene, BP) and photothermal functional structures (bionic, nanoarrays, HoMSs) in photothermal catalytic CO2 reduction from the regulation mechanism of sunlight absorption, photothermal conversion, active site exposure and carrier migration, and further proposed the potential application value of photothermal functional materials and structures in photothermal catalytic CO2 reduction. Finally, a critical review of how all-weather photothermal catalytic CO2 reduction breaks through the barrier of darkness, carbon pollution and inhibition of high temperature inactivation under concentrating light, and critical insights into the development direction, research progress, cautions, and future development opportunities of photothermal catalytic CO2 reduction from laboratory to industrialization are presented.
科研通智能强力驱动
Strongly Powered by AbleSci AI