化学
电化学发光
电催化剂
生物标志物
纳米技术
检出限
电化学
色谱法
电极
物理化学
生物化学
材料科学
作者
Y. Wu,Lixin Xu,Juan Yang,Shenglan Hu,Dongmiao Qin,Biyang Deng
标识
DOI:10.1021/acs.analchem.4c04014
摘要
The development of coreaction accelerators with excellent performance is crucial for improving electrochemiluminescence (ECL) performance. In this study, a NiFe nanoalloy electrocatalyst (NiFe-NAEC) was used as a coreaction accelerator to promote persulfate activation, resulting in a 44-fold increase in the ECL intensity of flower-like Zn-3,4,9,10-perylenetetracarboxylate (FL-Zn-PTC). Moreover, the synergistic combination of NiFe-NAEC and silver nanoparticles led to a 134-fold increase in the ECL intensity of FL-Zn-PTC, with a 6275% improvement in the ECL efficiency compared with a reference system containing Ru-bpy/K
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