材料科学
共轭体系
聚合物
窄带
有机发光二极管
光电子学
半最大全宽
部分
量子效率
荧光
纳米技术
光学
复合材料
有机化学
化学
物理
图层(电子)
作者
Wenbo Luo,Tao Wang,Zhongyan Huang,Haoxin Huang,Nengquan Li,Chuluo Yang
标识
DOI:10.1002/adfm.202310042
摘要
Abstract The development of thermally activated delayed fluorescence (TADF) polymers with narrowband emission, particularly in the blue region, remains a formidable challenge. Herein, a new approach is demonstrated for blue TADF conjugated polymers by integrating multiresonance TADF moiety into the conjugated backbone. All the new polymers exhibit TADF characteristics with narrowband blue emission with full‐width at half‐maximums (FWHMs) of 23 nm. The solution‐processed OLEDs based on these polymers achieve a maximum external quantum efficiency (EQE max ) of 17.9% with the emission peak at 479 nm and FWHM of 28 nm. The main‐chain type MR‐TADF polymer shed light on the development of narrowband emissive TADF conjugated polymers.
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