Mechanical responsive visible structural colors based on chiral-nematic cellulose nanocrystals photonic hydrogels

It has been extensively reported that cellulose nanocrystals (CNCs) are capable of exhibiting structural colors due to their unique chiral nematic self-assembly. However, further investigation is required to effectively utilize these remarkable properties for addressing real-world challenges, such as development of advanced materials like mechanical sensors and smart wearable devices. One particular challenge has been maintaining the refractive properties of structural colors resulting from the CNCs structure within the visible spectrum. In this study, we introduce a one-step hydrogel fabrication method involving chiral nematic CNC films embedded within poly(acrylic acid). These hydrogels exhibit naked-eye-visible structural colors and exhibit responsiveness to mechanical stresses. The resulting photonic hydrogels exhibit a blue shift in response to mechanical stretching. The hydrogels demonstrated self-recovery capabilities, as observed through cyclic loading–unloading stress tests. The color of the materials was characterized using UV–Vis spectroscopy to determine the wavelength of the reflected light. Additionally, we investigated the mechanism of CNCs orientation change using 2D-X-ray diffraction. Demonstrated by our simulation study, the morphology of the CNC bundles significantly influenced the characteristics of the chiral nematic structure as they orient due to the force application. Notably, the color change of the photonic hydrogels was reversible within the optimal range of applied force and can be repeated numerous times. This work presents a new strategy for fabricating optically functional photonic hydrogels with stimuli-responsive properties, enabling their potential applications in biomedical engineering and wearable responsive sensor technologies.