锂(药物)
电解质
电化学
氧化物
阴极
硫化物
材料科学
快离子导体
纳米技术
化学
冶金
电气工程
工程物理
工程类
电极
物理化学
医学
内分泌学
作者
Zhihui Xu,Xiaohu Wang,Li Wang,Xuelei Li,Jingshun Liu,Aruuhan Bayaguud,Lianqi Zhang
标识
DOI:10.1016/j.jpowsour.2023.233079
摘要
All–solid–state lithium batteries (ASSLBs) using sulfide solid electrolytes (SSEs) have triggered extensive attentions in both academia and industry due to the feasibility of effectuating high safety and high energy density, compared with liquid–type batteries. Cathode materials with high voltage and prominent specific capacity are urgently needed for realizing lithium batteries with high energy density. Among multitudinous cathode materials studied by researchers, Ni–rich layered oxide cathode materials are considered to be one of the most promising applications in ASSLBs due to high operating voltage, superior reversible capacity and low production cost. However, their physical, chemical, and electrochemical performances in ASSLBs, especially the long–life capacity, are still insufficient to gratify market requirements for electric vehicles, and the targeted review for Ni–rich layered oxide cathodes in ASSLBs is rare. Herein, we comprehensively summarize these issues of the interfacial physical connection, chemical/electrochemical reactions, and space–charge layer (SCL) of Ni–rich layered oxide cathodes in ASSLBs with SSEs. Moreover, the modification strategies of Ni–rich layered oxide cathode materials to address the aforementioned issues are focused on. In the end, the future development direction of ASSLBs using Ni-rich oxide cathodes and SSEs is briefly discussed.
科研通智能强力驱动
Strongly Powered by AbleSci AI