红土
黄钾铁矾
烘烤
镍
冶金
材料科学
锂(药物)
硫酸铵
背景(考古学)
铁合金
化学
无机化学
地质学
医学
内分泌学
古生物学
作者
Longjiao Chang,Anlu Wei,Shaohua Luo,Xiaolong Bi,Wei Yang,Ruifen Yang,Jianan Liu
标识
DOI:10.1016/j.jallcom.2022.168078
摘要
In the context of the COVID-19 pandemic and the war between Russia and Ukraine, domestic oil prices have skyrocketed. Saving resources and develop lithium ion batteries with excellent performance are particularly important. In view of unreasonable utilization of non-target elements in laterite nickel ore and high energy consumption of traditional sulfate roasting laterite nickel ore, a pioneering idea was adopted to combine laterite nickel ore with LiFePO4, which not only meets the resource saving but also prepares lithium ion batteries with excellent performance, in this study. Using ammonium sulfate roasting laterite nickel ore-ammonium jarosite iron precipitation and hydrolysis preparation of Fe2O3-carbon thermal reduction preparation of LiFePO4/C process means, to achieve the ultimate goal of preparing LiFePO4 from laterite nickel ore. Determining the optimum conditions of each part of experiment by single factor experiment and orthogonal experiment. It was concluded that under the optimal preparation conditions, the discharge specific capacity of lithium ion battery was 164.56 mAh/g at the rate of 0.5 C, and it was 94% of the theoretical capacity. After 100 cycles, we could find that the discharge specific capacity could be maintained at 162.78 mAh/g, and the capacity retention rate still reached 98%.
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