Isomer of NU-1000 with a Blocking c-pore Exhibits High Water–Vapor Uptake Capacity and Greatly Enhanced Cycle Stability

Chemically and hydrolytically stable metal-organic frameworks (MOFs) have shown great potential for many water-adsorption-related applications. However, MOFs with large pores that show high water-uptake capacity and high hydrolytic and mechanical cycle stability are rare. Through a deliberate adjustment of the linker of a typical zirconium-based MOF (Zr-MOF) (