膜
纳滤
材料科学
纺纱
复合材料
极限抗拉强度
纤维
渗透
化学工程
分馏
聚丙烯腈
聚合物
色谱法
化学
生物化学
工程类
作者
Zhiyong Chu,Kaikai Chen,Changfa Xiao,Dawei Ji,Haoyang Ling,Muyang Li,Hailiang Liu
标识
DOI:10.1016/j.jtice.2019.12.009
摘要
Loose nanofiltration (NF) hollow fiber membranes with excellent dye rejection and high inorganic salt transmission are promising for textile wastewater treatment. Herein, a novel kind of reinforced PES loose NF hollow fiber membranes with robust twisted fiber bundle was fabricated by a facile dry-wet spinning process. The SEM results indicate that the favorable interfacial bonding layer was formed between the separation and supporting layer for the sake of endowing the membranes with high longitudinal strength and lateral pressure resistance. For one thing, the tensile strength of the PST membranes was up to 185.7 MPa, a considerably higher than FEP hollow fiber membrane prepared by melt spinning process (18.5 MPa). Moreover, the PST-1 membranes show almost no deformation, compared to sever deformation of FEP hollow fiber membrane after 100 h at high pressure operation. For another, the prepared PST membranes display stable pure water flux of 52.3 L·m−2·h−1 under 0.6 MPa. Specifically, the PST membranes exhibit excellent fractionation efficiency of dye/salt mixtures, along with high dye rejection of 99.9% and low salt rejection (<7%). These results indicate that the robust reinforced PES loose NF hollow fiber membranes with permeation stability have great potential application for practical textile wastewater treatment.
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