Silver Nanowire Top Electrodes in Flexible Perovskite Solar Cells using Titanium Metal as Substrate

Abstract Flexible perovskite solar cells (FPSCs) have various applications such as wearable electronic textiles and portable devices. In this work, we demonstrate FPSCs on a titanium metal substrate employing solution‐processed silver nanowires (Ag NWs) as the top electrode. The Ag NW electrodes were deposited on top of the spiro‐MeOTAD hole transport layer by a carefully controlled spray‐coating method at moderate temperatures. The power conversion efficiency (PCE) reached 7.45 % under AM 1.5 100 mW cm −2 illumination. Moreover, the efficiency for titanium‐based FPSCs decreased only slightly (by 2.6 % of the initial value) after the devices were bent 100 times. With this and other advances, fully solution‐based indium‐free flexible photovoltaics, advantageous in terms of price and processing, have the potential to be scaled into commercial production.