钙质的
电化学
阴极保护
海水
电极
电流密度
材料科学
铜
降水
冶金
化学
矿物学
地质学
物理化学
海洋学
物理
古生物学
气象学
量子力学
作者
Yuho Jin,Thien Vuong Nguyen,R. E. White,Richard Griffin
出处
期刊:Journal of The Electrochemical Society
[The Electrochemical Society]
日期:1993-03-01
卷期号:140 (3): 733-742
被引量:75
摘要
A first principle mathematical model of the formation of calcareous deposits on a cathodically protected steel rotating disk electrode in seawater is presented. The model includes equations which transport phenomena, electrochemical reactions, precipitation reactions, and a homogeneous reaction involved in the formation of calcareous deposits on an electrode surface. Predicted concentration profiles show that a high concentration of OH− ions on the electrode surface leads to the formation of calcareous deposits. The calcareous deposits contain mostly , but the initial deposits are predicted to contain more than . The predicted calcareous deposits on the electrode surface reduce the active surface area available for the electrochemical reactions, which results in a decrease in the cathodic current density. The predicted current density as a function of time during the formation of deposits agrees qualitatively with experimental data.
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