丙醇
正丙醇
水溶液
化学
材料科学
热力学
物理化学
有机化学
物理
甲醇
作者
Fong-Meng Pang,Chye‐Eng Seng,Tjoon Tow Teng,Mahamad Hakimi Ibrahim
标识
DOI:10.1016/j.molliq.2007.01.003
摘要
Densities and viscosities of the binary aqueous solutions of 1-propanol and 2-propanol have been measured over the whole composition range at temperatures between 293.15 K and 333.15 K. The energies of activation for viscous flow for aqueous solutions of 1-propanol and 2-propanol were calculated and found to be 17.94 and 22.16 kJ mol− 1, respectively. A polynomial equation and an equation based on the Power Law and Erying's absolute rate theory were used to correlate the viscosity data of the aqueous solutions of 1-propanol and 2-propanol. The average absolute deviations (AAD) for density correlations of aqueous solutions of 1-propanol and 2-propanol are less than 0.07%.
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