超导电性
铜
氧化物
氧化铜
镍
过渡金属
凝聚态物理
钴
图层(电子)
转变温度
金属
材料科学
离子
结晶学
物理
无机化学
化学
冶金
纳米技术
有机化学
催化作用
作者
Kazunori Takada,H. Sakuraï,E. Takayama‐Muromachi,Fujio Izumi,Ruben A. Dilanian,Takayoshi Sasaki
出处
期刊:Nature
[Nature Portfolio]
日期:2003-03-01
卷期号:422 (6927): 53-55
被引量:1766
摘要
Since the discovery of high-transition-temperature (high-T(c)) superconductivity in layered copper oxides, many researchers have searched for similar behaviour in other layered metal oxides involving 3d-transition metals, such as cobalt and nickel. Such attempts have so far failed, with the result that the copper oxide layer is thought to be essential for superconductivity. Here we report that Na(x)CoO2*yH2O (x approximately 0.35, y approximately 1.3) is a superconductor with a T(c) of about 5 K. This compound consists of two-dimensional CoO2 layers separated by a thick insulating layer of Na+ ions and H2O molecules. There is a marked resemblance in superconducting properties between the present material and high-T(c) copper oxides, suggesting that the two systems have similar underlying physics.
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