阳极
水溶液
电解质
钠离子电池
钠
吸附
电池(电)
阴极
离子
无机化学
化学
化学工程
石墨烯
材料科学
纳米技术
有机化学
电极
物理化学
功率(物理)
法拉第效率
工程类
物理
量子力学
作者
Ravikumar Thimmappa,Manu Gautam,Shambhulinga Aralekallu,Mruthunjayachari Chattanahalli Devendrachari,Alagar Raja Kottaichamy,Zahid Manzoor Bhat,Musthafa Ottakam Thotiyl
标识
DOI:10.1002/celc.201900317
摘要
Abstract We report a rechargeable sodium‐ion battery in an aqueous environment with hydrophobic few‐layer graphene as the capacitive anode and hexacyanometallate as the insertion cathode. Owing to the lack of hydrophilic functionalities, sodium‐ion adsorption is selectively favored over H + adsorption at the hydrophobic anode/electrolyte interface without the complexity of widely encountered hydrogen‐ion insertion/H 2 evolution. Hydrophobicity precludes chemical bond formation with sodium ions, thereby improving reversibility and extended cyclability during charge discharge chemistry.
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