材料科学
介孔材料
化学工程
纳米技术
催化作用
介孔有机硅
纳米颗粒
介孔二氧化硅
有机化学
化学
工程类
作者
Lei Yu,Panpan Pan,Yu Zhang,Yi Zhang,Li Wan,Xiaowei Cheng,Yonghui Deng
出处
期刊:Small
[Wiley]
日期:2019-03-08
卷期号:15 (14)
被引量:49
标识
DOI:10.1002/smll.201805465
摘要
Abstract Using interfacial reaction systems for biphasic catalytic reactions is attracting more and more attention due to their simple reaction process and low environmental pollution. Yolk–shell structured materials have broad applications in biomedicine, catalysis, and environmental remediation owing to their open channels and large space for guest molecules. Conventional methods to obtain yolk–shell mesoporous materials rely on costly and complex hard‐template strategies. In this study, a mild and convenient nonsacrificial self‐template strategy is developed to construct yolk–shell magnetic periodic mesoporous organosilica (YS‐mPMO) particles by using the unique swelling–deswelling property of low‐crosslinking density resorcinol formaldehyde (RF). The obtained YS‐mPMO microspheres possess an amphiphilic outer shell, high surface area (393 m 2 g −1 ), uniform mesopores (2.58 nm), a tunable middle hollow space (50–156 nm), and high superparamagnetism (34.4–37.1 emu g −1 ). By tuning the synthesis conditions, heterojunction structured yolk–shell Fe 3 O 4 @RF@void@PMO particles with different morphologies can be produced. Owing to the amphipathy of PMO framworks, the YS‐mPMO particles show great emulsion stabilization ability and recyclability under a magnetic field. YS‐mPMO microspheres with immobilized Au nanoparticles (≈3 nm) act as both solid emulsifier for dispersing styrene (St) in water and interface catalysts for selective conversion of St into styrene oxide with a high selectivity of 86%, and yields of over 97%.
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