Geology and Geochemistry of the giant Huoshaoyun zinc-lead deposit, Karakorum Range, northwestern Tibet

The recently discovered giant Huoshaoyun zinc-lead deposit in the Karakorum Range, northwestern Tibet, China, consists of a major zinc-lead carbonate and a minor lead-dominant sulfide mineralization with metal reserves of zinc and lead of over 16 million tonnes. The zinc-lead carbonate mineralization is composed of smithsonite and cerussite, with laminated, massive, veined and botryoidal textures, showing sedimentary and metasomatic structures. The lead-dominant sulfide mineralization is composed mainly of galena and minor sphalerite and pyrite, with laminated, brecciated, and veined textures. The laminated sulfide mineralized zones occur at the top of the deposit, whereas the zinc-lead carbonate mineralized bodies are located below the sulfide zones. Lead-dominant sulfide veins cut the zinc-lead carbonate ores and the host limestone. The sequence of formation of the lead-zinc ores with various mineral colors in thin sections is as follows: (1) light-colored to yellowish, fine- to coarse- and subhedral to euhedral smithsonite; (2) yellowish to reddish, fine- to coarse- and subhedral to euhedral smithsonite; (3) light-colored veined smithsonite; (4) white coarse-grained, xenomorphic cerussite; (5) colorless euhedral to sub-angular quartz crystals; (6) euhedral to anhedral lead-zinc sulfides and gypsum. The mineralization events of the Huoshaoyun deposit are: (1) early hydrothermal sedimentary smithsonite mineralization; (2) hydrothermal replacive smithsonite mineralization; (3) vein-type smithsonite mineralization; (4) open space filling and replacive cerussite mineralization; (5) lead-zinc sulfide mineralization. The fluid inclusions of cerussite indicate that the hydrothermal fluids of the cerussite ore-forming stage are characterized by a temperature range of at least 186–206 °C and low salinities (0.7–1.2 wt% NaCl eq.). The source of oxygen and carbon for the zinc-lead carbonate mineralization is possibly consistent with the involvement of marine water and a magmatic fluid, and is probably dominated by the magmatic fluid. The source of sulfur for the lead-dominant sulfide mineralization is possibly related to a magma reservoir. The zinc-lead-carbonate portion of the deposit represents a primary hypogene non-sulfide mineralization.