Rational Construction of Highly Tunable Donor–Acceptor Materials Based on a Crystalline Host–Guest Platform

接受者 材料科学 分子 纳米技术 合理设计 化学 有机化学 凝聚态物理 物理
作者
Da‐Shuai Zhang,Qiang Gao,Ze Chang,Xiaoting Liu,Bin Zhao,Zhihong Xuan,Tong‐Liang Hu,Yinghui Zhang,Jian Zhu,Xian‐He Bu
出处
期刊:Advanced Materials [Wiley]
卷期号:30 (50) 被引量:131
标识
DOI:10.1002/adma.201804715
摘要

Organic donor-acceptor systems have attracted much attention due to their various potential applications. However, the rational construction and modulation of highly ordered donor-acceptor systems could be a challenge due to the complicated self-assembly process of donor and acceptor species. Considering the well-defined arrangement of species at the molecule level, a crystalline host-guest system could be an ideal platform for the rational construction of donor-acceptor systems. Herein, it is shown how the rational construction of highly tunable donor-acceptor materials can be achieved based on a crystalline host-guest platform. Within the well-established metal-organic framework NKU-111 as the crystalline host enabled by the relatively stable coordination-directed assembly, the introduction and arrangement of guest molecules in the crystals allow the rational construction of the NKU-111⊃guest donor-acceptor system. The donor-acceptor interaction in the systems can be readily modulated with different guest molecules, which can be justified by the well-demonstrated guest-dependent characteristics. Accordingly, the NKU-111⊃guest reveals highly tunable donor-acceptor properties such as charge-transfer-based emissions and electrical conductivity. This work indicates the potential of crystalline host-guest systems as an ideal platform for systematic investigations of donor-acceptor materials.
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