自愈水凝胶
吸附
水溶液
化学
丙烯酸酯
傅里叶变换红外光谱
聚丙烯酸钠
氯化铵
解吸
钠
聚合物
核化学
聚合
铵
氮气
高分子化学
肿胀 的
化学工程
有机化学
共聚物
原材料
工程类
作者
I-Chi Li,Yin-Hong Chen,Yung‐Chung Chen
标识
DOI:10.1016/j.jwpe.2022.102999
摘要
A series of interpenetrating polymer network sodium alginate-g-poly(sodium acrylate) (PASA) hydrogels (PASA-1, PASA-3, and PASA-5) were prepared through the thermal radical polymerization. Fourier transform infrared spectroscopy results revealed that all the hydrogels had been prepared successfully. The effects of various amounts of sodium alginate (SA) on various properties were investigated. When increasing the amount of SA in PASA polymer, the number of pores increased but the size of poores decreased. In addition, PASA hydrogels presenting crosslinking qualities exhibited relatively low swelling in water. Finally, the synthesized hydrogels were tested as adsorbents for ammonium chloride (NH4Cl) solution. The PASA-1 hydrogel exhibited the highest ammonia nitrogen adsorption capacity (12.9 mg/g), which 21.1 % higher than that of the reference poly(sodium acrylate) (PANa) hydrogel (10.7 mg/g) under similar conditions. The synthesized PASA-1 hydrogel exhibited satisfactory reusability and maintained 87 % of its adsorption capacity after nine cycles of ammonium nitrogen adsorption–desorption.
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