聚丙烯
马来酸酐
材料科学
高分子化学
胺气处理
热稳定性
退火(玻璃)
聚合物
复合材料
化学
有机化学
共聚物
作者
Henky Muljana,S. Arends,Klaas Remerie,Gert Boven,Francesco Picchioni,Ranjita K. Bose
出处
期刊:Polymers
[MDPI AG]
日期:2022-03-15
卷期号:14 (6): 1176-1176
被引量:3
标识
DOI:10.3390/polym14061176
摘要
In this work, the possibility of preparing cross-linked polypropylene (PP) via Diels−Alder (DA) chemistry is explored. The overall strategy involves reaction of maleated polypropylene (the starting material), furfuryl amine (FFA), and bismaleimide (BM) as the cross-linking agent. The occurrence of reversible cross-linking was studied by checking the presence of relevant peaks in FTIR spectra, i.e., CH out-of-plane bending vibrations of the furan ring’s peak (γCH) at an absorption band of 730−734 cm−1, CH=CH of the BM aromatic ring’s stretching vibrations (υCH=CH) at an absorption band of 1510 cm−1, and the DA adduct (C-O-C, δDAring) at an absorption band of 1186 cm−1. In agreement with the spectroscopic characterization, the presence of a cross-linked network is also confirmed by rheology, namely the higher storage modulus (G′) compared with loss modulus (G″) value (G′ >> G″), as obtained via temperature sweep. Both the maleic anhydride (MA) content as well as the annealing temperature (50 °C and 120 °C) favor the DA reaction, while only partial de-cross-linking (retro DA) is observed at the higher temperature range of 150−200 °C. In addition, the products show higher mechanical robustness and thermal stability compared to the starting material.
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