纤维素
转化(遗传学)
碳化
材料科学
化学工程
高分子科学
电流变液
纳米技术
化学
复合材料
有机化学
扫描电子显微镜
电场
物理
工程类
量子力学
基因
生物化学
作者
Tomáš Plachý,Erika Kutálková,David Škoda,Pavlína Holčapková
摘要
In this study, cellulose was carbonized in two-steps using hydrothermal and thermal carbonization in sequence, leading to a novel carbonaceous material prepared from a renewable source using a sustainable method without any chemicals and, moreover, giving high yields after a treatment at 600 °C in an inert atmosphere. During this treatment, cellulose was transformed to uniform microspheres with increased specific surface area and, more importantly, conductivity increased by about 7 orders of magnitude. The successful transition of cellulose to conducting carbonaceous microspheres was confirmed through SEM, FTIR, X-ray diffraction and Raman spectroscopy. Prepared samples were further used as a dispersed phase in electrorheological fluids, exhibiting outstanding electrorheological effects with yield stress over 100 Pa at an electric field strength 1.5 kV mm-1 and a particle concentration of only 5 wt%, significantly overcoming recent state-of-the-art findings. Impedance spectroscopy analysis showed clear interfacial polarization of this ER fluid with high dielectric relaxation strength and short relaxation time, which corresponded to increased conductivity of the particles when compared to pure cellulose. These novel carbonaceous particles prepared from renewable cellulose have further potential to be utilized in many other applications that demand conducting carbonaceous structures with high specific surface area (adsorption, catalyst, filtration, energy storage).
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