石墨氮化碳
光催化
介孔材料
材料科学
可见光谱
兴奋剂
化学工程
降级(电信)
碳纤维
氮化碳
氮化物
催化作用
纳米技术
光化学
化学
复合材料
光电子学
复合数
有机化学
电信
工程类
图层(电子)
计算机科学
作者
Fengping Hu,Wendong Luo,Yuying Hu,Hongling Dai,Xiaoming Peng
标识
DOI:10.1016/j.jallcom.2019.04.235
摘要
In this study, Phosphorus-doped mesoporous graphitic carbon nitride (P-mpg-C3N4) was successfully prepared by a facile simple thermal method. Microstructure and chemical properties of catalyst were studied by a series of characterization methods, the results showed that the P atoms were successfully doped on the structure of graphitic carbon nitride and uniformly distributed on the whole mesoporous nanostructure. And specific surface area of P-mpg-C3N4 can reach 198.3 m2/g, which is almost 10.7 times more than that of g-C3N4 (18.6 m2/g), pore diameter of P-mpg-C3N4 is mainly distributed in 2–20 nm and the average pore size is 11.3 nm. Photocatalytic degradation performance of the catalyst for brilliant ponceau 5R (BP-5R) in solution were studied under dark and visible light irradiation. The photocatalytic activity of P-mpg-C3N4 is about 31.1 times higher compared with that of g-C3N4, and about 3.9 times and 2.4 times than that of mpg-C3N4 and P-g-C3N4, respectively. Mechanism of its enhanced photocatalytic performance was mainly attributed to the synergistic effect of P-doping and fragmented mesoporous structure, on the one hand, which can extend visible light absorption range. On the other hand, it's can also promote the separation of photo-generated electron-hole pairs and accelerate the transfer of photo-generated electrons.
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