材料科学
石墨烯
钠离子电池
阴极
电池(电)
电化学
涂层
储能
电极
复合数
化学工程
纳米技术
复合材料
法拉第效率
物理
工程类
物理化学
功率(物理)
化学
量子力学
作者
Tianci Yuan,Yanxia Wang,Jiexin Zhang,Xiangjun Pu,Xinping Ai,Zhongxue Chen,Hanxi Yang,Yuliang Cao
出处
期刊:Nano Energy
[Elsevier]
日期:2018-11-08
卷期号:56: 160-168
被引量:166
标识
DOI:10.1016/j.nanoen.2018.11.011
摘要
Sodium-ion battery has emerged as one of most promising technologies for large-scale energy storage system, and hence has stimulated extensive exploration of applicable electrode materials with low cost and superb electrochemical properties. Herein, 3D graphene decorated Na4Fe3(PO4)2(P2O7) microspheres as a low-cost and environmentally friendly cathode material are synthesized by using a facile spray-drying method. The as-prepared [email protected] composite exhibits a high reversible capacity of 128 mAh g−1 at 0.1 C, a superior rate capability (35 mAh g−1 at 200 C), and a long cycling life (62.3% capacity retention over 6000 cycles at 10 C). The excellent electrochemical performance is attributed to combined advantages of graphene coating on the surface of nanoparticles and the flexible 3D graphene network, which not only improve the electronic conductivity, but also accommodate the structural stress of the material during charging and discharging. Therefore, the [email protected] microsphere with superior electrochemical performances, low-cost raw materials, simple synthetic route and high thermal stability is considered as a very attractive cathode electrode for sodium ion battery.
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