电解质
电极
Crystal(编程语言)
联轴节(管道)
电极电位
金属
单晶
标准电极电位
化学
功能(生物学)
曲面(拓扑)
工作(物理)
热力学
材料科学
化学物理
物理化学
计算机科学
结晶学
物理
数学
几何学
冶金
有机化学
进化生物学
生物
程序设计语言
标识
DOI:10.1016/0013-4686(91)85023-z
摘要
Existing experimental data have been reconsidered in the light of new conceptual approaches, and new data have been scrutinized with the purpose of offering new suggestions and new fundamental arguments for the theoretical modelling of the electrical double layer. The points touched on in this paper include: (1) the conceptual and quantitative relationship between electrode potential and work function measurements impacting on the experimental determination of the so-called “absolute” electrode potential; (2) the interfacial behaviour of Ag, Au and Cu compared with the group of sp-metals; (3) the temperature coefficient of Eσ = 0 for single crystal faces; (4) the inconsistency of the experimental and interpretative picture issuing from different laboratories in the case of single crystal faces of Ag. The general significance of the “interfacial parameter” ΔX as derived from Eσ = 0 vs Φ plots is discussed in particular. Such a parameter includes electronic and solvent effects and measures the degree of coupling between the metal surface and the solvent. It is shown that ΔX can arrange the various metals and the different crystal faces into a common picture.
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