纳米反应器
碳纳米管
脱氢
纳米技术
纳米颗粒
催化作用
材料科学
化学工程
多相催化
吸附
化学
有机化学
工程类
作者
Melad Shaikh,Ekrambaram Balaraman
出处
期刊:Acs Symposium Series
日期:2020-01-01
卷期号:: 459-481
被引量:2
标识
DOI:10.1021/bk-2020-1359.ch015
摘要
Design and development of new catalytic systems for sustainable catalysis are extremely important. Of late, carbon nanotubes (CNTs) have garnered attention as fascinating materials in sustainable catalytic transformation, because of their interesting morphological features. Such reactions are catalyzed either by the individual cylinders that work as both catalysts and nanoreactors or by additional catalytic species that are confined within the CNT channel. In confinement catalysis, the catalytic reactions occur mainly in the CNT channels and exterior surfaces of CNTs. A number of steps are involved, such as adsorption, dissemination, and reaction on the dynamic surface of nanoparticles and formation of the products. In this chapter, we discuss recent advances in using confinement of nanoparticles in CNTs as an efficient catalyst for sustainable chemical reactions (hydrogenation, oxidation, oil refining, biofuels from biomass, Fischer–Tropsch synthesis, dehydrogenation, and asymmetric catalysis).
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