Activated carbon versus metal-organic frameworks: A review of their PFAS adsorption performance

Perfluoroalkyl and polyfluoroalkyl substances (PFAS) are a class of fluorinated aliphatic compounds considered as emerging persistent pollutants. Owing to their adverse effects on human health and environment, efficient methods of their removal from various complex matrices need to be developed. This review focuses on recent results addressing the adsorption of PFAS on activated carbons (AC) and metal-organic frameworks (MOF). While the former are well-established adsorbents used in water treatment, the latter are relatively new and still not applied at a large scale. Nevertheless, they attract research interests owing to their developed porosity and versatile surface chemistry. While AC provide high volumes of pores and hydrophobic surfaces to strongly attract fluorinated chains, MOF supply sites for acid-base complexation and a variety of specific interactions. The modifications of AC are focused on the introduction of basicity to attract PFAS anions via electrostatic/chemical interactions, and those of MOF - on structural defects to increase the pore sizes. Based on the comparison of the performance and specifically adsorption forces provided by these two groups of materials, activated carbons were pointed out as worthy of further research efforts. This is because their surface, especially that in large pores, where dispersive forces are week and where extensive pore space might be utilized to adsorb more PFAS, can be further chemically modified and these modifications might be informed by the mechanisms of PFAS adsorption, which are specific for MOF. This review emphasizes the effects of these modifications on the adsorption mechanism and brings the critical assessment of the advantages/disadvantages of both groups as PFAS adsorbents.