N-Oxide as a Traceless Oxidizing Directing Group: Mild Rhodium(III)-Catalyzed CH Olefination for the Synthesis ofortho-Alkenylated Tertiary Anilines

Doppelrolle: In einer neuartigen, RhIII-katalysierten Synthese ortho-alkenylierter tertiärer Aniline fungiert eine spurlose dirigierende Gruppe zugleich als internes Oxidans (siehe Schema). Ein fünfgliedriger cyclometallierter RhIII-Komplex wird als plausible Zwischenstufe vorgeschlagen und konnte durch Röntgenstrukturanalyse charakterisiert werden. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.